Beta-Barium Borate (β-BaB2O4) or (BBO)
Structural and Physical Properties | ||||
Crystal Structure | Trigonal, space group R3c | |||
Cell Parameters | A = b = 12.532 Å | |||
C = 12.717 Å | ||||
Z = 6 | ||||
Melting Point | 1095 ± 5°C | |||
Transsition temperature | 925 ± 5°C | |||
Optical homogeneity | ?ddn ? 10-6 /cm | |||
Mohs Hardness | 4 | |||
Density | 3.85 g/cm3 | |||
Absorption Coefficient | < 0.1 %/cm ( at 1064 nm ) | |||
Specific hea: | 1.91 J/cm3 x K | |||
Hygrocopic susceptibility | Low | |||
Thermal expansion Coefficients. | a, 4 x 10-6 /K c, 36 x 10-6 /K |
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Thermal Conductivity | ^c, 1.2 W/m/K; //c, 1.6 W/m/K |
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Linear Optical Properties | ||||
Transparency range | 189 - 3500 nm | |||
Refractive indices | at 1064 nm | ne = 1.5425 | no = 1.6551 | |
at 532 nm | ne = 1.5555 | no = 1.6749 | ||
at 266 nm | ne = 1.6146 | no = 1.7571 | ||
Therm - optic Coefficients. | dno / dt = -9.3 x 10-6 /°C | |||
dne / dt = -16.6 x 10-6 /°C | ||||
Nonlinear Optical Properties | ||||
Phase - matchable output Wavelenghts | 189 - 1750 nm | |||
NLO Coefficients | d11 = 5.8 x d36 (KDP) | |||
d31 = 0.05 x d11 | ||||
d22 = 0.05 x d11 | ||||
Electro - Optic Coefficients | ???11 = 2.7 pm/V, ???22, ???31 <0.1 ???11 | |||
Half - wave voltage | 48 KV (at 1064 nm) | |||
Damage threshold | at 1064 nm | 5 GW / cm2 (10 ns) |
10 GW / cm2 (1.3 ns) |
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at 532 nm | 1 GW / cm2 (10 ns) |
7 GW / cm2 (250 ns) |
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List of optical crystals |
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